A Lab on a Chip Experiment for Upscaling Diffusivity of Evolving Porous Media

نویسندگان

چکیده

Reactive transport modelling is a powerful tool to assess subsurface evolution in various energy-related applications. Upscaling, i.e., accounting for pore scale heterogeneities into larger analyses, remains one of the biggest challenges reactive modelling. Pore simulations capturing evolutions porous media over wide range Peclet and Damköhler number combination with machine learning are foreseen as an efficient methodology upscaling. However, accuracy these models needs be tested against experiments. In this work, we developed lab on chip experiment novel micromodel design combined operando confocal Raman spectroscopy, monitor undergoing coupled mineral dissolution precipitation processes due diffusive fluxes. The 3D-imaging enabled derivation upscaled parameters. chemical reaction involved replacement celestine by strontianite, whereby net porosity increase expected because smaller molar volume strontianite. under our experimental conditions, accessible consequently diffusivity decreased. We propose transferability concepts behind Verma Pruess relationship applied also describe changes evolving media. Our results highlight importance calibrating quantitative experiments prior numbers which can further used

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Multilevel Upscaling in Heterogeneous Porous Media

The multiscale structure of heterogeneous porous media prevents a straightforward numerical treatment of the underlying mathematical ow models. In particular, fully resolved ow simulations are intractable and yet the ne-scale structure of a porous medium may signiicantly innuence the coarse-scale properties of the solution (e.g., average ow rates). Consequently, homogenization or upscaling proc...

متن کامل

Radiation in Porous Media: an Upscaling Methodology

The radiative properties of any porous medium are statistically defined by a cumulated extinction distribution function, a cumulated absorption probability and a bidirectional phase function. These functions are obtained by a Monte Carlo technique, from both the medium morphology data, known or issued from a X or γ ray tomography, and the radiative properties at a scale lower than the tomograph...

متن کامل

a study on thermodynamic models for simulation of 1,3 butadiene purification columns

attempts have been made to study the thermodynamic behavior of 1,3 butadiene purification columns with the aim of retrofitting those columns to more energy efficient separation schemes. 1,3 butadiene is purified in two columns in series through being separated from methyl acetylene and 1,2 butadiene in the first and second column respectively. comparisons have been made among different therm...

Upscaling for Two-phase Flows in Porous Media

The understanding and modeling of flow through porous media is an important issue in several branches of engineering. In petroleum engineering, for instance, one wishes to model the “enhanced oil recovery” process, whereby water or steam is injected into an oil saturated porous media in an attempt to displace the oil so that it can be collected. In groundwater contaminant studies the transport ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Energies

سال: 2022

ISSN: ['1996-1073']

DOI: https://doi.org/10.3390/en15062160